Synthesis and structure determination of the linear conjugated polyynyl and polyynediyl iron complexes Fp-(C C)(n)-X (X = H) (n = 1, 2); X = Fp (n = 1, 2, 4); Fp* = (eta(5)-C5Me5)Fe(CO)(2))

被引：117

作者：

Akita, M

Chung, MC

Sakurai, A

Sugimoto, S

Terada, M

Tanaka, M

Morooka, Y

机构：

[1] Res. Lab. of Resources Utilization, Tokyo Institute of Technology, Midori-ku, Yokohama 226

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 22期

关键词：

D O I：

10.1021/om970538m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of polyynyl and polyynediyl complexes of iron, Fp*-(C triple bond C)(n)-H (n=2) and Fp*-(C triple bond C)(n)-Fp* (n=2, 4; Fp*=(eta(5)-C5Me5)Fe(CO)(2)), have been prepared, and their linear structure has been confirmed by X-ray crystallography.

引用

页码：4882 / 4888

页数：7

共 63 条

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Synthesis and structure determination of the linear conjugated polyynyl and polyynediyl iron complexes Fp*-(C C)(n)-X (X = H) (n = 1, 2); X = Fp* (n = 1, 2, 4); Fp* = (eta(5)-C5Me5)Fe(CO)(2))

Synthesis and structure determination of the linear conjugated polyynyl and polyynediyl iron complexes Fp-(C C)(n)-X (X = H) (n = 1, 2); X = Fp (n = 1, 2, 4); Fp* = (eta(5)-C5Me5)Fe(CO)(2))