Fabrication and electrochemical properties of three-dimensional net architectures of anatase TiO2 and spinel Li4Ti5O12 nanofibers

被引:69
作者
Lu, Hai-Wei
Zeng, Wei
Li, Yue-Sheng
Fu, Zheng-Wen [1 ]
机构
[1] Fudan Univ, Shanghai Key Lab Mol Catalysts & Innovat Mat, Dept Mat Sci, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysts & Innovat Mat, Dept Mat Sci, Laser Chem Inst, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
electrospinning; three-dimensional rechargeable lithium ion batteries; nanofibers; TiO2; Li4Ti5O12;
D O I
10.1016/j.jpowsour.2006.11.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
As a new type of electrodes engineering method with three-dimensional (3D) architecture for 3D rechargeable lithium ion batteries, an electrospinning has been successfully employed to prepare 3D net architectures of anatase TiO2 and spinel Li4Ti5O12 nanofibers. Scanning electron microscopy, X-ray diffraction, cyclic voltammetry and the discharge/charge measurements were used to characterize their structures and electrochemical properties. Our results demonstrated that 3D architectures stacked from a cross-bar array of electrospun anatase TiO2 nanofibers could be accomplished but were destroyed after the insertion of Li ion. Significantly, spinel Li4Ti5O12 could be selected as one of promise candidates for the realization of 3D batteries considering its structure stability of 3D spinel Li4Ti5O12 nanotibers associated with well cyclability. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:874 / 879
页数:6
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