Lithiation characteristics of FeVO4

被引：26

作者：

Hayashibara, M

Eguchi, M

Miura, T

Kishi, T

机构：

来源：

SOLID STATE IONICS | 1997年 / 98卷 / 1-2期

关键词：

FeVO4; lithium insertion; ESR; Mossbauer spectrum;

D O I：

10.1016/S0167-2738(97)00107-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lithiation behaviour of one of iron (III)-vanadium (V) complex oxides, FeVO4, was investigated, focusing an attention on its redox nature and structural changes upon lithiation. It was revealed that lithiation of FeVO4 occurs through three steps. Primary single phase lithiation occurs at 0<x<0.3. Further lithiation causes a formation of LiFeO2 and presumably VO2, and VO2 will be further reduced.

引用

页码：119 / 125

页数：7

共 11 条

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