Formation of carbocycles through sequential carborhodation triggered by addition of organoborons

被引：241

作者：

Miura, Tomoya ^{[1
]}

Murakami, Masahiro ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 03期

关键词：

RHODIUM-CATALYZED ADDITION; INTRAMOLECULAR NUCLEOPHILIC-ADDITION; CROSS-COUPLING REACTIONS; N-TERT-BUTANESULFINYL; ARYLBORONIC ACIDS; ASYMMETRIC 1,4-ADDITION; CONJUGATE ADDITION; BORONIC ACIDS; ARYLATIVE CYCLIZATION; ALKENYLBORONIC ACIDS;

D O I：

10.1039/b609991b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article highlights recent developments in the formation of carbocycles via multiple carborhodation steps triggered by the rhodium-catalysed intermolecular addition of organoborons. Various types of cascade reactions have been developed to demonstrate that multiple carborhodation steps can precede potentially competing processes such as protonolysis.

引用

收藏

页码：217 / 224

页数：8

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