Boron-nitrogen coordination polymers bearing ferrocene in the main chain

被引:90
作者
Grosche, M
Herdtweck, E
Peters, F
Wagner, M
机构
[1] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
[2] Tech Univ Munich, Inst Anorgan Chem, D-85747 Munich, Germany
关键词
D O I
10.1021/om990594i
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of 1, 1'-fc(BMe2)(2) (2) with pyrazine gives a novel poly(ferrocene) [2.pyz](n), which has been. structurally characterized by X-ray crystallography [fc = (C5H4)(2)Fe; pyz = pyrazine]. The unusual dark green. color of the solid material is indicative of charge-transfer interactions between the iron centers and the electron-poor pyrazine adduct bridges.
引用
收藏
页码:4669 / 4672
页数:4
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