Boron-nitrogen coordination polymers bearing ferrocene in the main chain

被引：90

作者：

Grosche, M

Herdtweck, E

Peters, F

Wagner, M

机构：

[1] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany

[2] Tech Univ Munich, Inst Anorgan Chem, D-85747 Munich, Germany

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 22期

关键词：

D O I：

10.1021/om990594i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1, 1'-fc(BMe2)(2) (2) with pyrazine gives a novel poly(ferrocene) [2.pyz](n), which has been. structurally characterized by X-ray crystallography [fc = (C5H4)(2)Fe; pyz = pyrazine]. The unusual dark green. color of the solid material is indicative of charge-transfer interactions between the iron centers and the electron-poor pyrazine adduct bridges.

引用

页码：4669 / 4672

页数：4

共 23 条

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