Identification of flame retardants in polymers using curie point pyrolysis-gas chromatography/mass spectrometry

被引：14

作者：

Riess, M

Thoma, H

Vierle, O

van Eldik, R

机构：

[1] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91058 Erlangen, Germany

[2] Bavarian State Off Protect Environm, D-81901 Munich, Germany

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2000年 / 53卷 / 02期

关键词：

polymers; gas chromatography; curie point pyrolysis; pyrolysis;

D O I：

10.1016/S0165-2370(99)00062-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A rapid method for the qualitative identification of technical flame retardants in polymers originating from electronic waste, is described using curie-point pyrolysis gas chromatography with mass spectrometric detection. For a series of samples, the pyrolysis products of the flame retardants were studied as a function of the pyrolysis temperature. Identification of the flame retardants was achieved on the basis of a comparison with synthetic and pure flame retardant standards. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：135 / 148

页数：14

共 19 条

[1] GAS-CHROMATOGRAPHIC IDENTIFICATION OF POLYMERS USING INDIVIDUAL PYROLYSIS PRODUCTS [J].

ALEKSEEVA, KV .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1980, 2 (01) :19-34

[2]

Blazso M, 1998, RAPID COMMUN MASS SP, V12, P1, DOI 10.1002/(SICI)1097-0231(19980115)12:1<1::AID-RCM106>3.0.CO

[3]

2-N

[4] In-line process monitoring on polymer melts by NIR-spectroscopy [J].

Fischer, D ;

Bayer, T ;

Eichhorn, KJ ;

Otto, M .

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1997, 359 (01) :74-77

[5]

FISCHER WG, 1993, LC GC INT, V6, P760

[6]

Gachter R, 1993, PLASTIC ADDITIVES HD

[7]

LORENTZ W, 1993, CHEMOSPHERE, V12, P2221

[8]

MAY RW, 1977, ANAL SCI MONOGRAPHS

[9] STUDY ON THERMAL-DEGRADATION OF POLYSTYRENES BY PYROLYSIS-GAS CHROMATOGRAPHY AND PYROLYSIS FIELD-IONIZATION MASS-SPECTROMETRY [J].

OHTANI, H ;

YUYAMA, T ;

TSUGE, S ;

PLAGE, B ;

SCHULTEN, HR .

EUROPEAN POLYMER JOURNAL, 1990, 26 (08) :893-899

[10]

RIESS M, 1998, ORGANOHAL COMPD, V35, P443

← 1 2 →