Characterization of supercooling suppression of microencapsulated phase change material by using DSC

被引:97
作者
Alvarado, J. L.
Marsh, C.
Sohn, C.
Vilceus, M.
Hock, V.
Phetteplace, G.
Newell, T.
机构
[1] Texas A&M Univ, Dept Engn Technol & Ind Distribut, College Stn, TX 77843 USA
[2] USA, Engineer Res & Dev Ctr, Construct Engn Res Lab, Champaign, IL 61822 USA
[3] USA, Cold Reg Res & Engn Lab, Engineer Res & Dev Ctr, Hanover, NH 03755 USA
[4] Univ Illinois, Dept Mech & Ind Engn, Urbana, IL 61801 USA
关键词
cooling rate; crystallization point; DSC; latent heat of fusion; melting point; microencapsulated phase change material;
D O I
10.1007/s10973-005-7430-0
中图分类号
O414.1 [热力学];
学科分类号
摘要
Supercooling suppression of microencapsulated n-tetradecane was measured using differential scanning calorimetry. Results indicate that the degree of supercooling is positively affected by the amount and type of nucleating agent present in bulk and microencapsulated n-tetradecane which it is used as a phase change material (MPCM). Results also demonstrate that the melting point of the n-tetradecane is fairly independent of nucleating agent concentration (0 - 4%). Conversely, the latent heat of fusion of n-tetradecane decreases considerably with nucleating agent amount and the initiation of crystallization point is inversely proportional to cooling rate.
引用
收藏
页码:505 / 509
页数:5
相关论文
共 28 条
[1]  
ALVARADO JL, 2004, THESIS U ILLINOIS UR
[2]  
ALVARADO JL, 2005, P 2005 ASME INT MECH
[3]   Influence of CaCO3 nanoparticles shape on thermal and crystallization behavior of isotactic polypropylene based nanocomposites [J].
Avella, M ;
Cosco, S ;
Di Lorenzo, ML ;
Di Pace, E ;
Errico, ME .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 80 (01) :131-136
[4]   Heat transfer and pressure drop of ice slurries in plate heat exchangers [J].
Bellas, J ;
Chaer, I ;
Tassou, SA .
APPLIED THERMAL ENGINEERING, 2002, 22 (07) :721-732
[5]   Tetradecane and hexadecane binary mixtures as phase change materials (PCMs) for cool storage in district cooling systems [J].
Bo, H ;
Gustafsson, EM ;
Setterwall, F .
ENERGY, 1999, 24 (12) :1015-1028
[6]   FORCED-CONVECTION HEAT-TRANSFER IN MICROENCAPSULATED PHASE-CHANGE MATERIAL SLURRIES - FLOW IN CIRCULAR DUCTS [J].
CHARUNYAKORN, P ;
SENGUPTA, S ;
ROY, SK .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 1991, 34 (03) :819-833
[7]  
CHOI E, 1991, INT COMMUN HEAT MASS, V18, P759, DOI 10.1016/0735-1933(91)90027-2
[8]  
CHOI E, 1993, THESIS DREXEL U
[9]   THERMAL-ANALYSIS OF THE MIXTURE OF LABORATORY AND COMMERCIAL GRADES HEXADECANE AND TETRADECANE [J].
CHOI, ES ;
CHO, YI ;
LORSCH, HG .
INTERNATIONAL COMMUNICATIONS IN HEAT AND MASS TRANSFER, 1992, 19 (01) :1-15
[10]  
CHOI ES, 1994, INT J HEAT MASS TRAN, V37, P207, DOI 10.1016/0017-9310(94)90093-0