Nitrogen oxidation states elucidated by X-ray absorption nitrogen K-edge spectroscopy.

被引：17

作者：

do Nascimento, Gustavo M. ^{[1
]}

Temperini, Marcia L. A. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05513970 Sao Paulo, Brazil

来源：

QUIMICA NOVA | 2006年 / 29卷 / 04期

关键词：

NK XANES; poly(aniline); dyes;

D O I：

10.1590/S0100-40422006000400033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The potentialities of X-ray Absorption Near Edge Spectroscopy (XANES) of the N K edge (N K) obtained with the spherical grating monochromator beam line at the Brazilian National Synchrotron Light Laboratory are explored in the investigation of poly(aniline), nanocomposites and dyes. Through the analysis of N K XANES spectra of conducting polymers and many other dye compounds that are dominated by 1s ->pi* transitions, it was possible to correlate the band energy value with the nitrogen oxidation states. An extensive N K XANES spectral database was obtained, thus permitting the elucidation of the nature of different nitrogens present in the intercalated conducting polymers.

引用

页码：823 / 828

页数：6

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