Effect of texture and surface chemistry on adsorptive capacities of activated carbons for phenolic compounds removal

被引:47
作者
Ania, CO [1 ]
Parra, JB [1 ]
Pis, JJ [1 ]
机构
[1] CSIC, Inst Nacl Carbon, Oviedo 33080, Spain
关键词
activated carbon; phenol; salicylic acid; adsorptive capacities;
D O I
10.1016/S0378-3820(02)00072-3
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Three microporous commercial activated carbons (AC) were used for the adsorption of phenol and salicylic acid from aqueous solution. Equilibrium adsorption data were obtained by the bottle-point technique. Long periods of time were needed to reach the equilibrium between the active carbon and the aqueous solution. Adsorptive capacities obtained from the isotherms were calculated following the ASTM 3860 procedure. Carbons with a high oxygen content were found to present lower adsorptive capacities for both phenol and salicylic acid. Column tests were also used for the uptake of phenol and salicylic acid, and adsorptive capacities were calculated from the breakthrough curves. Adsorptive capacities calculated from the breakthrough curves were found to be significantly lower than those evaluated from the equilibrium isotherms. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:337 / 343
页数:7
相关论文
共 16 条
[1]  
*ASTM, 3860 ASTM D
[2]  
Gillogly TET, 1999, J AM WATER WORKS ASS, V91, P98
[3]  
HILL A, 1968, CARBON, V16, P31
[4]   IODINE ADSORPTION AND STRUCTURE OF ACTIVATED CARBONS [J].
JUHOLA, AJ .
CARBON, 1975, 13 (05) :437-442
[5]   Effects of surface properties of activated carbons on adsorption on behavior of selected aromatics [J].
Leng, CC ;
Pinto, NG .
CARBON, 1997, 35 (09) :1375-1385
[6]  
LIU KT, 1981, J WATER POLLUT CON F, V53, P1541
[7]  
MENEDEZ JA, 1992, CARBON, V30, P797
[8]   ADSORPTION OF SOME SUBSTITUTED PHENOLS ON ACTIVATED CARBONS FROM A BITUMINOUS COAL [J].
MORENOCASTILLA, C ;
RIVERAUTRILLA, J ;
LOPEZRAMON, MV ;
CARRASCOMARIN, F .
CARBON, 1995, 33 (06) :845-851
[9]   Interaction of aqueous solutions of phenol with commercial activated carbons:: an adsorption and kinetic study [J].
Nevskaia, DM ;
Santianes, A ;
Muñoz, V ;
Guerrero-Ruíz, A .
CARBON, 1999, 37 (07) :1065-1074
[10]   ESTIMATION OF THE POINT OF ZERO CHARGE OF SIMPLE OXIDES BY MASS TITRATION [J].
NOH, JS ;
SCHWARZ, JA .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1989, 130 (01) :157-164