Cascade complexation of pseudo-halide by dicopper cryptates: A linear Cu-NNN-Cu unit

被引：95

作者：

Harding, CJ

Mabbs, FE

MacInnes, EJL

McKee, V

Nelson, J

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

[2] OPEN UNIV,DEPT CHEM,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND

[3] UNIV MANCHESTER,EPSRC EPR SERV CTR,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 15期

关键词：

D O I：

10.1039/dt9960003227

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An X-ray crystallographic structure determination of a mu-azido azacryptate has confirmed the existence of collinear Cu-NNN-Cu geometry, earlier cited as the origin of unusual spectroscopy in dicopper mu-azido cryptates; the isoelectronic mu-cyanato cryptate is also isostructural.

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页码：3227 / 3230

页数：4

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