Synthetic approaches to C-glucosinolates

被引：20

作者：

Aucagne, V

Gueyrard, D

Tatibouët, A

Quinsac, A

Rollin, P

机构：

[1] Univ Orleans, Inst Chim Organ & Analyt, F-45067 Orleans 2, France

[2] CETIOM, F-45160 Olivet, France

来源：

TETRAHEDRON | 2000年 / 56卷 / 17期

关键词：

glucosinolates; myrosinase inhibition; C-glycosides; Horner-Emmons reaction;

D O I：

10.1016/S0040-4020(00)00153-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In these pages, short and efficient synthetic approaches to C-analogs of glucosinolates are described. Starting from D-glucose, C-glucotropaeolin (6) and C-glucocapparin (11) were synthesized in three steps. Preliminary enzymatic assays involving sulfatase and myrosinase have been performed. (C) 2000 Published by Elsevier Science Ltd. All rights reserved.

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收藏

页码：2647 / 2654

页数：8

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