Bis(propane-1,3-diaminium) tris(pyridine-2,6-dicarboxylato-κ3O,N,O′)cerate(III) nitrate 3.5-hydrate

被引：16

作者：

Aghabozorg, Hossein ^{[1
]}

Nakhjavan, Bahar ^{[1
]}

Ghadermazi, Mohammad ^{[1
]}

Ramezanipour, Farshid ^{[1
]}

机构：

[1] Teacher Training Univ, Dept Chem, Tehran 15614, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

COORDINATION POLYMERS; FRAMEWORK; COMPLEXES; LA(III); SYSTEM; CE;

D O I：

10.1107/S1600536806021404

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, (C3H12N2)(2)[Ce(C7H3NO4)(3)](NO3)center dot-3.5H(2)O, is a nine-coordinate Ce complex obtained from a proton-transfer compound. The molecular structure contains three pyridine-2,6-dicarboxylate species as tridentate ligands and two propane-1,3-diaminium cations as counter-ions. The asymmetric unit also contains one nitrate anion and 3.5 uncoordinated water molecules. In the crystal structure, a wide range of hydrogen-bonding interactions connect the various fragments into a supramolecular structure.

引用

页码：M1527 / M1529

页数：3

共 10 条

[1] A proton transfer compound: propane-1,3-diaminium-pyridine-2,6-dicarboxylate - pyridine-2,6-dicarboxylic acid-water (2/2/2/5) [J].

Aghabozorg, H ;

Ghadermazi, M ;

Ramezanipour, F .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 :O1143-O1146

[2] 2,6-Diaminopyridinium pyridinium-2,6-dicarboxylate: a redetermination [J].

Aghabozorg, H ;

Saei, AA ;

Ramezanipour, F .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :O3242-O3244

[3]

[Anonymous], 1998, SAINT PLUS VERS 6 01

[4]

[Anonymous], 1998, SADABS VERSION 2 01

[5] Hydrothermal investigation of the lanthanide (Ln = La, Ce, Pr, Nd, Sm) 2,6-pyridinedicarboxylate system [J].

Brouca-Cabarrecq, C ;

Fernandes, A ;

Jaud, J ;

Costes, JP .

INORGANICA CHIMICA ACTA, 2002, 332 :54-60

[6] Coordination polymers of La(III) as bunched infinite nanotubes and their conversion into an open-framework structure [J].

Ghosh, SK ;

Bharadwaj, PK .

INORGANIC CHEMISTRY, 2005, 44 (09) :3156-3161

[7] Self-assembly of lanthanide helicate coordination polymers into 3D metal-organic framework structures [J].

Ghosh, SK ;

Bharadwaj, PK .

INORGANIC CHEMISTRY, 2004, 43 (07) :2293-2298

[8] A novel pillar-layered organic-inorganic hybrid based on lanthanide polymer and polyomolybdate clusters:: New opportunity toward the design and synthesis of porous framework [J].

Lü, J ;

Shen, EH ;

Li, YG ;

Xiao, DR ;

Wang, EB ;

Xu, L .

CRYSTAL GROWTH & DESIGN, 2005, 5 (01) :65-67

[9] Synthesis, characterization, and X-ray crystal structures of Co(II) and La(III) complexes of a pyridine containing self-assembling system and solution studies of the Co(II) complex [J].

Moghimi, A ;

Ranjbar, M ;

Aghabozorg, H ;

Jalali, F ;

Shamsipur, M ;

Chadha, KJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2002, 80 (12) :1687-1696

[10] Synthesis and crystal structure of CeIII and BiIII complexes and solution studies of ZnII, CdII, PdII, CeIII, and BiIII complexes obtained from proton transfer compounds containing 2,6-pyridinedicarboxylate ion [J].

Sheshmani, S ;

Kheirollahi, PD ;

Aghabozorg, H ;

Shokrollahi, A ;

Kickelbick, G ;

Shamsipur, M ;

Ramezanipour, F ;

Moghimi, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (15) :3058-3065

← 1 →