Thermal behaviour of some rhodium(II) cycloalkanocarboxylate complexes

被引:5
作者
de Souza, AR
Najjar, R
Matos, JR
机构
[1] UFG, Inst Quim, BR-74001970 Goiania, Go, Brazil
[2] Univ Sao Paulo, Inst Quim, BR-05383970 Sao Paulo, Brazil
关键词
rhodium(II) carboxylates; carboxylates; cycloalkanocarboxylates; rhodium oxides;
D O I
10.1016/S0040-6031(99)00316-0
中图分类号
O414.1 [热力学];
学科分类号
摘要
Thermal properties of cycloalkanecarboxylates [Rh-2(O2CR)(4)] (R = C3H5, C4H7, C5H9 and C6H11) were studied and the results compared with those obtained for [Rh-2(O2CR)(4)] (R = CH3, C2H5 and C3H7). Thermogravimetry and differential scanning calorimetry were used as the techniques and the heats of reaction for the samples in open and closed crucibles were obtained, in different atmospheres. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:119 / 125
页数:7
相关论文
共 11 条
[1]   Thermal behaviour and isothermal kinetics of rhodium(II) acetate [J].
Braga, MM ;
Yoshida, MI ;
Sinisterra, RD ;
Carvalho, CF .
THERMOCHIMICA ACTA, 1997, 296 (1-2) :141-148
[2]  
Brown M., 1980, COMPREHENSIVE CHEM K, V22
[3]   DIAGNOSIS OF THE NATURE OF CARBOXYLATE COORDINATION FROM THE DIRECTION OF SHIFTS OF CARBON OXYGEN STRETCHING FREQUENCIES [J].
DEACON, GB ;
HUBER, F ;
PHILLIPS, RJ .
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 104 (01) :41-45
[4]   THERMAL-DECOMPOSITION OF DIMETHYL-SULFOXIDE AND PYRIDINE ADDUCTS OF RHODIUM(II) ACETATE, PROPIONATE AND BUTYRATE [J].
HOWARD, RA ;
WYNNE, AM ;
BEAR, JL ;
WENDLANDT, WW .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1976, 38 (05) :1015-1018
[5]  
*INT CTR DIFF DAT, 1988, POWD DIFF FIL IN PHA
[6]   A STUDY OF SOME RHODIUM(2) ACETATE ADDUCTS [J].
KITCHENS, J ;
BEAR, JL .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1969, 31 (08) :2415-&
[7]  
KITCHENS J, 1970, THERMOCHIM ACTA, V1, P537
[8]  
KITCHENS J, 1969, J INORG NUCL CHEM, V32, P49
[9]  
KOCHERGINA LL, 1980, RUSS J INORG CHEM, V255, P354
[10]  
Rempel A., 1972, ganic Syntheses, P90