Carbon nanotube-filled polycarbonate composites produced by melt mixing and their use in blends with polyethylene

被引:246
作者
Pötschke, P [1 ]
Bhattacharyya, AR [1 ]
Janke, A [1 ]
机构
[1] Inst Polymer Res Dresden, D-01069 Dresden, Germany
关键词
carbon nanotubes; composites; melt mixing; polycarbonate; electrical conductivity; dispersion;
D O I
10.1016/j.carbon.2003.12.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper presents composites of polycarbonate (PC) having different amounts of multiwalled carbon nanotubes (MWNT). The composites were prepared by diluting a masterbatch of PC with 15 wt% MWNT using melt mixing in a DACA-Micro Compounder. Electrical resistivity measurements indicated percolation of MWNT between 1 and 1.5 wt%. Transmission electron microscopy (TEM) showed excellent dispersion of the MWNT and indicated no preferred orientation of MWNT in extrusion direction. In addition, a conductive PC-2 wt% MWNT composite was melt mixed with polyethylene in order to get co-continuous blends exhibiting double percolation. Significant reduction in electrical resistivity of the blends could be achieved in compositions down to 30 vol% filled PC in which the total MWNT content was only 0.41 vol%. These blends exhibited co-continuous structures. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:965 / 969
页数:5
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