Gas composition in laser pyrolysis of hydrocarbon-based mixtures: Influence on soot morphology

被引:38
作者
Morjan, I
Voicu, I
Alexandrescu, R
Pasuk, I
Sandu, I
Dumitrache, F
Soare, I
Fleaca, TC
Ploscaru, M
Ciupina, V
Daniels, H
Westwood, A
Rand, B
机构
[1] Natl Inst Lasers Plasma & Radiat Phys, Laser Dept, R-76900 Bucharest, Romania
[2] Res Inst Elect Engn Adv Res, Bucharest 74204, Romania
[3] Ovidius Univ Constanta, Constanta, Romania
[4] Univ Leeds, Sch Proc Environm & Mat Engn, Mat Res Inst, Leeds LS2 9TT, W Yorkshire, England
关键词
fullerene; soot; pyrolysis; x-ray diffraction; reactivity;
D O I
10.1016/j.carbon.2004.01.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Laser pyrolysis of hydrocarbons leads to soots containing different carbon nanostructures. The investigations of carbon nanopowders revealed the presence of the amorphous carbon, carbon with small graphitic sheets or fullerene-like structures. The soot morphology depends on the gas mixture and experimental parameters. The role of oxygen is essential in obtaining soot particles having considerable curved-layer content. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1269 / 1273
页数:5
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