Ti-ferrierite and TiITQ-6:: synthesis and catalytic activity for the epoxidation of olefins with H2O2

被引:54
作者
Corma, A [1 ]
Diaz, U [1 ]
Domine, ME [1 ]
Fornés, V [1 ]
机构
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
关键词
D O I
10.1039/a908748f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new zeolitic material TiITQ-6 has been obtained by the direct synthesis of a layered titanosilicate precursor, followed by delamination; titanium is tetrahedrally coordinated in framework positions and, while the zeolite derived from the precursor has little activity owing to geometrical constraints, the delaminated TiITQ-6 material is active and selective for the epoxidation of hex-1-ene with H2O2.
引用
收藏
页码:137 / 138
页数:2
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