Gold(I)-catalyzed formation of 5-methylene-1,3-oxazolidin-2-ones

被引：108

作者：

Buzas, Andrea ^{[1
]}

Gagosz, Fabien ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, UMR 7652, DCSO,Lab Synth Organ, F-91128 Palaiseau, France

来源：

SYNLETT | 2006年 / 17期

关键词：

gold catalysis; ring closure; oxazolidinones;

D O I：

10.1055/s-2006-950253

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A study concerning the gold(I)-catalyzed rearrangement of propargylic tert-butylcarbamates into 5-methylene-1,3-oxazolidin-2-ones is described. The mild reaction conditions employed allow the efficient synthesis of a variety of these structures, which would be less conveniently obtained using other reported methods.

引用

页码：2727 / 2730

页数：4

共 34 条

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