Cumulated advantages of enzymatic and carbene chemistry for the non-organometallic synthesis of (co)polyesters

被引:11
作者
Xiao, Yan [1 ]
Coulembier, Olivier [2 ]
Koning, Cor E. [1 ]
Heise, Andreas [1 ,3 ]
Dubois, Philippe [1 ,2 ]
机构
[1] Eindhoven Univ Technol, NL-5600 MB Eindhoven, Netherlands
[2] Univ Mons, Lab Polymer & Composite Mat, CIRMAP, B-7000 Mons, Belgium
[3] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland
基金
爱尔兰科学基金会;
关键词
RING-OPENING POLYMERIZATION; CHEMOENZYMATIC CASCADE POLYMERIZATION; BLOCK-COPOLYMERS; POLYESTERS;
D O I
10.1039/b819624a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Enzymatic and carbene catalysed ring opening polymerisation can be combined in a one-pot reaction for the metal-free synthesis of degradable block copolymers.
引用
收藏
页码:2472 / 2474
页数:3
相关论文
共 12 条
[1]  
COULEMBIER O, 2005, ANGEW CHEM INT EDIT, V44, P4694
[2]   Insights into the initiation process of enzymatic ring-opening polymerization from monofunctional alcohols using liquid chromatography under critical conditions [J].
de Geus, Matthijs ;
Peters, Ron ;
Koning, Cor E. ;
Heise, Andreas .
BIOMACROMOLECULES, 2008, 9 (02) :752-757
[3]   Block copolymers by chemoenzymatic cascade polymerization: A comparison of consecutive and simultaneous reactions [J].
De Geus, Matthijs ;
Schormans, Linda ;
Palmans, Anjar. A. ;
Koning, Cor E. ;
Heise, Andreas .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (14) :4290-4297
[4]   Controlled ring-opening polymerization of lactide and glycolide [J].
Dechy-Cabaret, O ;
Martin-Vaca, B ;
Bourissou, D .
CHEMICAL REVIEWS, 2004, 104 (12) :6147-6176
[5]   L,L-lactide and ε-caprolactone block copolymers by a 'poly(L,L-lactide) block first' route [J].
Florczak, Marcin ;
Libiszowski, Jan ;
Mosnacek, Jaroslav ;
Duda, Andrzej ;
Penczek, Stanislaw .
MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (13) :1385-1391
[6]  
KALRA B, 2005, ACS S SERIES, V900
[7]   Organocatalytic ring-opening polymerization [J].
Kamber, Nahrain E. ;
Jeong, Wonhee ;
Waymouth, Robert M. ;
Pratt, Russell C. ;
Lohmeijer, Bas G. G. ;
Hedrick, James L. .
CHEMICAL REVIEWS, 2007, 107 (12) :5813-5840
[8]   Enzymatic ring-opening polymerization and atom transfer radical polymerization from a bifunctional initiator [J].
Meyer, U ;
Palmans, ARA ;
Loontjens, T ;
Heise, A .
MACROMOLECULES, 2002, 35 (08) :2873-2875
[9]   One-pot chemoenzymatic cascade polymerization under kinetic resolution conditions [J].
van As, BAC ;
Thomassen, P ;
Kalra, B ;
Gross, RA ;
Meijer, EW ;
Palmans, ARA ;
Heise, A .
MACROMOLECULES, 2004, 37 (24) :8973-8977
[10]   Enzyme catalyzed synthesis of polyesters [J].
Varma, IK ;
Albertsson, AC ;
Rajkhowa, R ;
Srivastava, RK .
PROGRESS IN POLYMER SCIENCE, 2005, 30 (10) :949-981