High-pressure effects in the homogeneously catalyzed hydroformylation of olefins

被引：15

作者：

Albers, J ^{[1
]}

Dinjus, E ^{[1
]}

Pitter, S ^{[1
]}

Walter, O ^{[1
]}

机构：

[1] Forschungszentrum Karlsruhe, ITC CPV, D-76021 Karlsruhe, Germany

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 219卷 / 01期

关键词：

hydroformylation; rhodium; high-pressure; homogeneous catalysis;

D O I：

10.1016/j.molcata.2004.04.028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The homogeneously catalyzed hydroformylation of linear olefins was investigated at pressures ranging from 7 to 550 MPa. A change in the selectivity was observed, which was reflected by a change of the product distribution. At high-pressures, increased yields of aldehydes were also obtained from the hydroformylation of sterically hindered olefins. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：41 / 46

页数：6

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