Soluble, saturated-red-light-emitting poly(p-phenylenevinylene) containing triphenylamine units and cyano groups

被引：20

作者：

Li, HC ^{[1
]}

Hu, YF ^{[1
]}

Zhang, YG ^{[1
]}

Ma, DG ^{[1
]}

Wang, LX ^{[1
]}

Jing, XB ^{[1
]}

Wang, FS ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 16期

关键词：

conjugated polymers; cyano groups; light-emitting diodes (LED); Knoevenagel condensation; poly(p-phenylenevinylene) (PPV); red-light-emitting polymers; triphenylamine; fluorescence;

D O I：

10.1002/pola.20278

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A conjugated poly(p-CN-phenylenevinylene) (PCNPV) containing both electron-donating triphenylamine units and electron-withdrawing cyano groups was prepared via Knoevenagel condensation in a good yield. Gel permeation chromatography suggested that the soluble polymer had a very high weight-average molecular weight of 309,000. A bright and saturated red emission was observed under UV excitation in solution and film. Cyclic voltammetry showed that the polymer presented quasi-reversible oxidation with a relatively low potential because of the triphenylamine unit. A single-layer indium tin oxide/PCNPV/Mg-Ag device emitted a bright red light (633 nm). (C) 2004 Wiley Periodicals, lnc.

引用

页码：3947 / 3953

页数：7

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