Analysis of stereodynamical effects in terms of order parameters and steric factors

被引:8
作者
Busalla, A
Blum, K
机构
[1] Inst. für Theoretische Physik I, Universität Münster, D-48149 Münster
关键词
D O I
10.1021/jp970411a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
General equations are derived for differential cross sections for collisions between anisotropic molecular ensembles and electrons or atoms. In the obtained expressions geometrical and dynamical factors are separated. The initial anisotropic axis distribution is characterized by ''order parameters''; the information on the dynamics is contained in ''steric factors''. The results can be used to analyze experimental results and also as a basis for numerical calculations. Several examples are discussed in order to point out the geometrical importance of the relevant parameters for diatomic and polyatomic molecules. As an illustration, all relevant steric factors are numerically calculated for elastic collisions between electrons and anisotropic ensembles of CO molecules.
引用
收藏
页码:7476 / 7485
页数:10
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