Soluble aromatic polyamides containing the phenylindane group and their gas transport characteristics

被引:29
作者
Ding, Y [1 ]
Bikson, B [1 ]
机构
[1] Innovat Membrane Syst Inc, Norwood, MA 02062 USA
关键词
polyamides; gas transport; phenylindane;
D O I
10.1016/S0032-3861(02)00276-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A series of new polyamides containing the phenylindane moiety was synthesized from 3-(4-carboxyphenyl)-2,3-dihydro-1,1,3-trimethyl-1H-indene-5-carboxylic acid and aromatic diamines by the direct phosphorylation polymerization method. The phenylindane moiety containing polyamides are highly soluble in polar aprotic solvents, such as DMF, DMAc, and NMP, and exhibit very high glass transition temperatures and attractive gas separation characteristics, i.e. high gas permeability coefficients combining with high gas separation factors. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4709 / 4714
页数:6
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