An apparatus to determine the rovibrational distribution of molecular hydrogen formed by the heterogeneous recombination of H atoms on cosmic dust analogues

被引:33
作者
Perry, JSA [1 ]
Gingell, JM [1 ]
Newson, KA [1 ]
To, J [1 ]
Watanabe, N [1 ]
Price, SD [1 ]
机构
[1] UCL, Dept Chem, London WC1H 0AJ, England
关键词
REMPI; molecular hydrogen formation; interstellar medium; heterogeneous chemistry; graphite; atom-surface interaction; hydrogen atom;
D O I
10.1088/0957-0233/13/9/306
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An experiment has been constructed to determine the rovibrational states populated in the formation of H-2 on the surface of cosmic dust under conditions approaching those of the interstellar medium (ISM). During the experiment, a beam of atomic hydrogen of controlled temperature is incident upon a target which is an analogue of cosmic dust. Molecular hydrogen desorbing from the target's surface is ionized using (2 + 1) resonance enhanced multiphoton ionization and detected using time-of-flight mass spectrometry. The experiment allows the rovibrational populations of the H-2 molecules desorbing from the cosmic dust targets to be determined providing information on the energy budget of the H-2 formation process in the ISM. Preliminary results from the experiment, to prove its viability, show that H-2 molecules formed on an highly oriented pyrolytic graphite surface have a measurable population of excited vibrational and rotational states.
引用
收藏
页码:1414 / 1424
页数:11
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