Archimedean solids: Transition metal mediated rational self-assembly of supramolecular-truncated tetrahedra

被引：96

作者：

Leininger, S ^{[1
]}

Fan, J ^{[1
]}

Schmitz, M ^{[1
]}

Stang, PJ ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2000年 / 97卷 / 04期

关键词：

D O I：

10.1073/pnas.030264697

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

A family of nanoscale-sized supramolecular cage compounds with a polyhedral framework is prepared by self-assembly from tritopic building blocks and rectangular corner units via noncovalent coordination interactions. These highly symmetrical cage compounds are described as face-directed, self-assembled truncated tetrahedra with T-d symmetry.

引用

页码：1380 / 1384

页数：5

共 54 条

[1] Dicatechol ligands: novel building-blocks for metallo-supramolecular chemistry [J].