UV absorption spectrum of ozone: Structure analysis and study of the isotope effect in the Hartley system

被引：24

作者：

Parisse, C

Brion, J

Malicet, J

机构：

[1] URA D 1434 Spectrometrie Molec./A., Moulin de la Housse, 51062 Reims

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 248卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(95)01259-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Apart from its crucial role in the atmosphere, particularly in filtering solar radiation in the UV wavelength region by absorption in the well known Hartley and Huggins bands, ozone attracts spectroscopic interest regarding the interpretation of these bands. From the results of previous measurements in our laboratory, we have investigated the structures of the Hartley system for two isotopes (O-16(3) and O-18(3)). This analysis allows us to propose an absolute assignment and to give two sets of vibrational parameters for the excited electronic state of the two species.

引用

收藏

页码：31 / 36

页数：6

相关论文

共 20 条

[1] TEMPERATURE-DEPENDENCE OF THE OZONE ABSORPTION-COEFFICIENT IN THE HARTLEY CONTINUUM [J].

ASTHOLZ, DC ;

CROCE, AE ;

TROE, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (05) :696-699

[2] 3-DIMENSIONAL ANALYTICAL MODEL FOR THE PHOTODISSOCIATION OF SYMMETRICAL TRIATOMICS - ABSORPTION AND FLUORESCENCE-SPECTRA OF OZONE [J].

ATABEK, O ;

BOURGEOIS, MT ;

JACON, M .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (12) :6699-6711

[3] THEORETICAL-STUDY OF THE GROUND AND EXCITED-STATES OF OZONE IN ITS SYMMETRICAL NUCLEAR ARRANGEMENT [J].

BANICHEVICH, A ;

PEYERIMHOFF, SD .

CHEMICAL PHYSICS, 1993, 174 (01) :93-109

[4] INFRARED-SPECTRA OF 16O3 AND 18O3 - DARLING AND DENNISON RESONANCE AND ANHARMONIC POTENTIAL FUNCTION OF OZONE [J].

BARBE, A ;

SECROUN, C ;

JOUVE, P .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1974, 49 (02) :171-182

[5]

BASS AM, 1984, P QUADRENNIAL OZONE

[6] HIGH-RESOLUTION LABORATORY ABSORPTION CROSS-SECTION OF O3 - TEMPERATURE EFFECT [J].

BRION, J ;

CHAKIR, A ;

DAUMONT, D ;

MALICET, J ;

PARISSE, C .

CHEMICAL PHYSICS LETTERS, 1993, 213 (5-6) :610-612

[7] OZONE UV SPECTROSCOPY .1. ABSORPTION CROSS-SECTIONS AT ROOM-TEMPERATURE [J].

DAUMONT, D ;

BRION, J ;

CHARBONNIER, J ;

MALICET, J .

JOURNAL OF ATMOSPHERIC CHEMISTRY, 1992, 15 (02) :145-155

[8]

FREEMAN DE, 1984, PLANET SPACE SCI, V32, P248

[9] GEOMETRIES AND ENERGIES OF EXCITED-STATES OF O-3 FROM ABINITIO POTENTIAL-ENERGY SURFACES [J].

HAY, PJ ;

DUNNING, TH .

JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (05) :2290-2303

[10] ABSORPTION OF OZONE IN ULTRA-VIOLET AND VISIBLE REGIONS OF SPECTRUM [J].

HEARN, AG .

PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1961, 78 (504) :932-&