Oxygen-17 nuclear magnetic resonance of organic solids

被引：40

作者：

Dong, S ^{[1
]}

Yamada, K ^{[1
]}

Wu, G ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 2000年 / 55卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

oxygen-17; solid state NMR; organic compounds; chemical shift tensor; quadrupole coupling constant;

D O I：

10.1515/zna-2000-1-205

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report solid-state O-17 NMR determinations of the oxygen chemical shift (CS) and electric field gradient (EFG) tensors for a series of O-17-enriched organic compounds containing various functional groups. In several cases, analysis of the O-17 magic-angle-spinning (MAS) and static NMR spectra yields both the magnitude and relative orientations of the O-17 CS and EFG tensors. We also demonstrate the feasibility of solid-state O-17 NMR as a potentially useful technique for studying molecular structure and hydrogen bonding.

引用

页码：21 / 28

页数：8

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