One-dimensional Cu(II) coordination polymers: tuning the structure by modulating the "carboxylate arm'' lengths of polycarboxylate ligands

被引：26

作者：

Abuhmaiera, Ramadan ^{[2
]}

Lan, Yanhua ^{[2
]}

Ako, Ayuk M. ^{[3
]}

Kostakis, George E. ^{[3
]}

Mavrandonakis, Andreas ^{[3
]}

Klopper, Wim ^{[3
]}

Clerac, Rodolphe ^{[1
,4
]}

Anson, Christopher E. ^{[2
]}

Powell, Annie K. ^{[2
,3
]}

机构：

[1] CNRS, Ctr Rech Paul Pascal, Equipe Mat Mol Magnet, UPR 8641, F-33600 Pessac, France

[2] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

[3] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[4] Univ Bordeaux, UPR 8641, F-33600 Pessac, France

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 06期

关键词：

METAL-ORGANIC FRAMEWORK; CYCLIC WATER PENTAMERS; SELF-ASSEMBLED CHAIN; MAGNETIC-PROPERTIES; SUPRAMOLECULAR COMPLEX; 2-DIMENSIONAL WATER; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; (H2O)(7) CLUSTER; DONOR LIGANDS;

D O I：

10.1039/b820834d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H(3)cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H(3)cpidp), have been synthesized. The reaction of each with Cu(NO3)(2) center dot 3H(2)O under similar reaction conditions yields two 1D coordination polymers {[Cu-3(cpiap)(2)(H2O)(3)](mu-H2O)}(n) center dot 7nH(2)O (1) and [Cu(H(2)cpidp)(2)(H2O)(2)](n) center dot 4nH(2)O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.

引用

页码：1089 / 1096

页数：8

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