Methyltrioxorhenium catalyzed oxidation of saturated and aromatic hydrocarbons by H2O2 in air

被引：68

作者：

Schuchardt, U ^{[1
]}

Mandelli, D ^{[1
]}

Shulpin, GB ^{[1
]}

机构：

[1] NN SEMENOV CHEM PHYS INST,MOSCOW 117977,RUSSIA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 36期

关键词：

D O I：

10.1016/0040-4039(96)01418-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkanes (cyclohexane, cyclooctane, n-heptane) and aromatic compounds (benzene, toluene, and ethylbenzene) are oxidized by anhydrous H2O2 in MeCN in air in the presence of catalytic amounts of MTO. The reaction is accelerated by addition of pyrazine-2-carboxylic acid. Alkanes give alkyl hydroperoxides as main products, as well as alcohols and ketones. Arenes yield predominantly phenols. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：6487 / 6490

页数：4

共 31 条

[1] OXIDATION OF METHOXYBENZENES TO P-BENZOQUINONES CATALYZED BY METHYLTRIOXORHENIUM(VII) [J].