Metal directed syntheses of metallocyclophanes containing triangular arrays of interacting redox active octahedral metal centres, X-ray crystal structure of [W(Tp*)(NO)(OC6H4O)](3)

被引：20

作者：

McQuillan, FS ^{[1
]}

Chen, HG ^{[1
]}

Hamor, TA ^{[1
]}

Jones, CJ ^{[1
]}

机构：

[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

来源：

POLYHEDRON | 1996年 / 15卷 / 21期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0277-5387(96)00168-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The trimeric metallocyclophanes [M(NO){HB(3,5-Me(2)C(3)HN(2))3}(O2C6H4)](3) (M = Mo, syn, syn-isomer; M = W, anti, syn-isomer) have been obtained from metal directed reactions involving the octahedral precursor complexes [M(NO){HB(3,5-Me(2)C(3)HN(2))(3)}I-2] and 1,4-dihydroxybenzene, the structure of the tungsten complex being confirmed by all X-ray diffraction study. Both compounds exhibit three well resolved reduction processes in their cycle voltammograms showing that they can exist in four distinct oxidation states. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：3909 / 3913

页数：5

共 25 条

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