Retention of configuration and regiochemistry in allylic alkylations via the memory effect

被引：47

作者：

Faller, JW ^{[1
]}

Sarantopoulos, N ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 09期

关键词：

D O I：

10.1021/om0306224

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The results of a systematic variation of achiral monodentate ligands used for the Pd-catalyzed alkylation of crotyl and 3-buten-2-yl acetates and carbonates are presented. A significant degree of retention of regiochemistry and stereochemistry was observed for these substrates, especially for nonracemic 3-buten-2-yl ethyl carbonate with PCyxPh3-x and carbene ligands.

引用

页码：2179 / 2185

页数：7

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