Preparation of nanowires of M substituted manganese dioxides (M=Al, Co, Ni) by the electrochemical-hydrothermal method

被引：11

作者：

Machefaux, E. ^{[1
]}

Verbaere, A. ^{[1
]}

Guyomard, D. ^{[1
]}

机构：

[1] Univ Nantes, CNRS, Lab Chim Solides, Inst Mat Jean Rouxel, F-44322 Nantes 3, France

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2006年 / 67卷 / 5-6期

关键词：

D O I：

10.1016/j.jpcs.2006.01.064

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of gamma-MnO2 compounds containing a metal M (with M = Al, Co or Ni) has been synthesized using the electrochemical-hydrothermal method. Depending on the selected synthesis parameters (temperature, pH, current density, presence of M) various structures and morphologies were obtained for the deposits. The experimental conditions allowing us to prepare M-containing gamma-MnO2 nanowires, and the structural and physico-chemical characteristics of the obtained samples are presented. The electrochemical Li insertion behavior of these M-containing gamma-MnO2 nanowires is briefly described. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1315 / 1319

页数：5

共 17 条

[1] STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF THE PROTON GAMMA-MNO2 SYSTEM [J].

CHABRE, Y ;

PANNETIER, J .

PROGRESS IN SOLID STATE CHEMISTRY, 1995, 23 (01) :1-130

[2] INTERPRETATION OF SOME GAMMA-MNO2 DIFFRACTION PATTERNS [J].

DEWOLFF, PM .

ACTA CRYSTALLOGRAPHICA, 1959, 12 (04) :341-&

[3] Synthesis, structural and electrochemical characterizations of the sol-gel birnessite MnO1.84•0.6H2O [J].

Franger, S ;

Bach, S ;

Farcy, J ;

Pereira-Ramos, JP ;

Baffier, N .

JOURNAL OF POWER SOURCES, 2002, 109 (02) :262-275

[4] Nanofibrous α-, β-, γ- and α•γ-manganese dioxides prepared by the hydrothermal- electrochemical technique -: I.: Synthesis and characterization [J].

Hill, LI ;

Verbaere, A ;

Guyomard, D .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (08) :D135-D148

[5] One-step electrochemical synthesis of α-MnO2 and α•γ-MnO2 compounds for lithium batteries [J].

Hill, LI ;

Portal, R ;

Verbaere, A ;

Guyomard, D .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (11) :A180-A183

[6] Electrochemical synthesis of beta- and gamma-manganese dioxides under hydrothermal conditions [J].

Hill, LI ;

Portal, R ;

La Salle, AL ;

Verbaere, A ;

Guyomard, D .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (06) :D1-D3

[7]

HILL LL, UNPUB

[8] Mechanisms of expression of HHV8, EBV and HPV in selected HIV-associated oral lesions [J].

Hille, JJ ;

Webster-Cyriaque, J ;

Palefski, JM ;

Raab-Traub, N .

ORAL DISEASES, 2002, 8 :161-168

[9] Synthesis and characterisation of new nanostructured manganese oxides for lithium batteries [J].

Machefaux, E ;

Verbaere, A ;

Guyomard, D .

IONICS, 2005, 11 (1-2) :24-28

[10]

MACHEFAUX E, UNPUB

← 1 2 →