Enantiospecific synthesis of a planar chiral fluorenylzirconium ansa-metallocene:: synthesis and structures of [1-(9-fluorenyl)- and [1-(1-methyl-9-fluorenyl)-2-(2-indenyl)naphthalene]zirconium dichloride

被引：18

作者：

Baker, RW ^{[1
]}

Foulkes, MA ^{[1
]}

Turner, P ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 04期

关键词：

D O I：

10.1039/a910246i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Di-lithiation of +ac(R)-1-methyl-9-[2-(2-indenyl)-1-naphthyl]fluorene, +ac(R)-6, generates an axially chiral fluorenyl ligand, (a-S)-10, which on reaction with ZrCl4 enantiospecifically provides the planar chiral ansa-zirconocene (p-S)-[1-(1-methyl-9-fluorenyl)-2-(2-indenyl)naphthalene]zirconium dichloride, (p-S)-8; single crystal X-ray structures have been determined for the racemic ansa-zirconocene rac-8 and the related C-s-symmetric ansa-zirconocene 7.

引用

收藏

页码：431 / 433

页数：3

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