p-triallylcalix[4]arene: The final member of the p-allylcalix[4] arenes

被引：20

作者：

Ho, ZC ^{[1
]}

Ku, MC ^{[1
]}

Shu, CM ^{[1
]}

Lin, LG ^{[1
]}

机构：

[1] CHINESE CULTURE UNIV,INST APPL CHEM,TAIPEI 11114,TAIWAN

来源：

TETRAHEDRON | 1996年 / 52卷 / 41期

关键词：

D O I：

10.1016/0040-4020(96)00786-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The heat-induced Claisen rearrangement of calix[4]arene triallyl ether 6a produced the title compound, p-triallylcalix[4]arene (7). The triallyl ether 6a was prepared from calix[4]arene 1,3-diallyl ether (1a) in a three-step process. Benzoylation of 1,3-diallyl ether 1a, under separate reaction conditions, resulted in the formation of either one of the isomeric pair of monobenzoates 2 or 3a. The allylation of 3a and subsequent debenzoylation yielded calix[4]arene triallyl ether 6a. The synthesis and structural assignment of these calix[4]arene derivatives are discussed. Further study of this four-step conversion for other calix[4]arene trialkyl ether derivatives is also presented. Copyright (C) 1996 Elsevier Science Ltd.

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页码：13189 / 13200

页数：12

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