Concave reagents 36:: Transition metal complexes with concave 1,10-phenanthrolines

被引：5

作者：

Gelbert, M

Körber, C

Friedrich, O

Fahrenkrug, F

Keller, M

Lüning, U

机构：

[1] Univ Kiel, Inst Organ Chem, D-24098 Kiel, Germany

[2] Univ Freiburg, Chem Lab, D-79104 Freiburg, Germany

来源：

SUPRAMOLECULAR CHEMISTRY | 2002年 / 14卷 / 2-3期

关键词：

transition metal complex; macrocycle; redox-system; concave ligands;

D O I：

10.1080/10610270290026013a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexes between concave 1,10-phenanthrolines 1 and transition metal ions (Mn2+, Fe2+, Fe (3+), Co2+, Ni2+ , Cu+ , Cu2+, Zn2+, Ag+, Cd2+) have been synthesized and characterized by various methods including UV titration, NMR spectroscopy, EPR spectroscopy, cyclovoltarnmetry, microanalysis and X-ray analysis. The concave 1,10-phenanthrolines 1 form 1:1 complexes with the metal ions while the complexes of analogous, but non-bimacrocyclic 1,10-phenanthrolines such as 2 and 2,9-dimethyl-1,10-phenanthroline exist in varying stoichiometries.

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页码：199 / 210

页数：12

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