Flavonolignans from Hyparrhenia hirta

被引:63
作者
Bouaziz, M
Veitch, NC [1 ]
Grayer, RJ
Simmonds, MSJ
Damak, M
机构
[1] Royal Bot Gardens, Jodrell Lab, Richmond TW9 3DS, Surrey, England
[2] Fac Sci Sfax, Lab Chim Subst Nat, Sfax 3018, Tunisia
关键词
Hyparrhenia hirta; Poaceae; flavonolignans; flavonolignan glycosides; tricin; NMR spectroscopy;
D O I
10.1016/S0031-9422(02)00145-0
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Leaves of Hyparrhenia hirta yielded the rare diastereoisomeric flavonolignans tricin 4'-O-(erythro-beta-guaiacylglyceryl) ether and tricin 4'-O-(threo-beta-guaiacylglyceryl) ether together with their 7-O-glucosides, which are the first flavonolignan glycosides to be isolated as natural products. A complete set of H-1 and C-13 NMR resonance assignments obtained for both flavonolignan aglycones indicates the need for revision of data published previously for these compounds and for a reassessment of their original stereochemical designation. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:515 / 520
页数:6
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