Stable superhydrophobic coatings from polyelectrolyte multilayers

被引:830
作者
Zhai, L
Cebeci, FÇ
Cohen, RE
Rubner, MF
机构
[1] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
[2] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA
[3] Tech Univ Istanbul, Dept Chem, TR-34469 Istanbul, Turkey
关键词
D O I
10.1021/nl049463j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present study demonstrates that the superhydrophobic behavior of the lotus leaf structure can be mimicked by creating a honeycomb-like polyelectrolyte multilayer surface overcoated with silica nanoparticles. Superhydrophobicity was achieved by coating this highly textured multilayer surface with a semifluorinated silane. The surface maintains its superhydrophobic character even after extended immersion in water. The key structural elements needed to create stable, superhydrophobic coatings from polyelectrolyte multilayers are discussed.
引用
收藏
页码:1349 / 1353
页数:5
相关论文
共 28 条
[1]   Purity of the sacred lotus, or escape from contamination in biological surfaces [J].
Barthlott, W ;
Neinhuis, C .
PLANTA, 1997, 202 (01) :1-8
[2]   Wettability of porous surfaces. [J].
Cassie, ABD ;
Baxter, S .
TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 :0546-0550
[3]   Ultrahydrophobic and ultralyophobic surfaces:: Some comments and examples [J].
Chen, W ;
Fadeev, AY ;
Hsieh, MC ;
Öner, D ;
Youngblood, J ;
McCarthy, TJ .
LANGMUIR, 1999, 15 (10) :3395-3399
[4]   Controlling the permeability of multilayered polyelectrolyte films through derivatization, cross-linking, and hydrolysis [J].
Dai, JH ;
Jensen, AW ;
Mohanty, DK ;
Erndt, J ;
Bruening, ML .
LANGMUIR, 2001, 17 (03) :931-937
[5]   Transformation of a simple plastic into a superhydrophobic surface [J].
Erbil, HY ;
Demirel, AL ;
Avci, Y ;
Mert, O .
SCIENCE, 2003, 299 (5611) :1377-1380
[6]  
Feng L, 2002, ANGEW CHEM INT EDIT, V41, P1221, DOI 10.1002/1521-3773(20020402)41:7<1221::AID-ANIE1221>3.0.CO
[7]  
2-G
[8]   Super-hydrophobic surfaces: From natural to artificial [J].
Feng, L ;
Li, SH ;
Li, YS ;
Li, HJ ;
Zhang, LJ ;
Zhai, J ;
Song, YL ;
Liu, BQ ;
Jiang, L ;
Zhu, DB .
ADVANCED MATERIALS, 2002, 14 (24) :1857-1860
[9]   Creation of a superhydrophobic surface from an amphiphilic polymer [J].
Feng, L ;
Song, YL ;
Zhai, J ;
Liu, BQ ;
Xu, J ;
Jiang, L ;
Zhu, DB .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (07) :800-802
[10]   Reversibly erasable nanoporous anti-reflection coatings from polyelectrolyte multilayers [J].
Hiller, J ;
Mendelsohn, JD ;
Rubner, MF .
NATURE MATERIALS, 2002, 1 (01) :59-63