Highly Selective Catalytic Conversion of Phenolic Bio-Oil to Alkanes

被引：588

作者：

Zhao, Chen ^{[2
]}

Kou, Yuan ^{[1
]}

Lemonidou, Angeliki A. ^{[2
,3
]}

Li, Xuebing ^{[2
]}

Lercher, Johannes A. ^{[2
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, PKU Green Chem Ctr, Beijing 100871, Peoples R China

[2] Tech Univ Munich, Dept Chem, D-85747 Garching, Germany

[3] Aristotle Univ Thessaloniki, Dept Chem Engn, Thessaloniki, Greece

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 22期

关键词：

aqueous-phase catalysis; bio-oil; heterogeneous catalysis; hydrodeoxygenation; palladium; RUTHENIUM NANOCLUSTER CATALYST; BIOMASS-DERIVED HYDROCARBONS; AQUEOUS-PHASE; PALLADIUM CATALYSTS; HYDROGENATION; HYDRODEOXYGENATION; CYCLOHEXANONE; DEACTIVATION; PRECURSORS; PLATINUM;

D O I：

10.1002/anie.200900404

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oil and water: A new energy-efficient and atom-economical catalytic route for the production of alkanes and methanol by upgrading the phenolic fraction of bio-oil has been developed. The onepot aqueous-phase hydrodeoxygenation process is based on two catalysts facilitating consecutive hydrogenation, hydrolysis, and dehydration reactions. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3987 / 3990

页数：4

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