Chelating of titanium by lactic acid in the water-soluble diammonium tris(2-hydroxypropionato)titanate(IV)

被引：75

作者：

Kakihana, M

Tomita, K

Petrykin, V

Tada, M

Sasaki, S

Nakamura, Y

机构：

[1] Tohoku Univ, Inst Multidisciplinary Res & Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan

[2] Tokyo Inst Technol, Mat & Struct Lab, Yokohama, Kanagawa 2268503, Japan

[3] Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 15期

关键词：

D O I：

10.1021/ic040031l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stable water-soluble diammonium tris(2-hydroxypropionato)titanate(IV) [ammonium trilactatotitanate(IV)], (NH4)(2)[Ti(C3H4O3)(3)], was prepared in the crystalline form. According to the X-ray single-crystal diffraction data, this compound crystallizes in the cubic cell with a = 11.649(4)Angstrom, space group P2(1)3 (no. 198), and has Z = 4 molecules per unit cell. The C-13 NMR data and Raman and IR spectra support the determined structure. The absence of nonbonded functional groups restricts the formation of oligomers in contrast to the reported speciation of citratoperoxotitanate(IV) complexes.

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页码：4546 / 4548

页数：3

相关论文

共 23 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[2]

Baskaran S, 1998, J AM CERAM SOC, V81, P401, DOI 10.1111/j.1151-2916.1998.tb02347.x

[3] Multilayered titania, silica, and Laponite nanoparticle coatings on polystyrene colloidal templates and resulting inorganic hollow spheres [J].

Caruso, RA ;

Susha, A ;

Caruso, F .

CHEMISTRY OF MATERIALS, 2001, 13 (02) :400-409

[4] CONFIGURATIONAL AND VICINAL CONTRIBUTIONS TO OPTICAL ACTIVITY OF ISOMERS OF TRIS(ALANINATO)COBALT(3) [J].

DOUGLAS, BE ;

YAMADA, S .

INORGANIC CHEMISTRY, 1965, 4 (11) :1561-&

[5] β-diketonate derivatives of titanium alkoxides:: X-ray crystal structures and solution dynamics of the binuclear complexes [{Ti(OR)3(dik)}2] [J].

Errington, RJ ;

Ridland, J ;

Clegg, W ;

Coxall, RA ;

Sherwood, JM .

POLYHEDRON, 1998, 17 (5-6) :659-674

[6] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)

[7] Morphology of titania coatings on silica gel [J].

Hanprasopwattana, A ;

Rieker, T ;

Sault, AG ;

Datye, AK .

CATALYSIS LETTERS, 1997, 45 (3-4) :165-175

[8] ''Sol-Gel'' preparation of high temperature superconducting oxides [J].

Kakihana, M .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1996, 6 (01) :7-55

[9] Structure and stability of water soluble (NH4)8[Ti4(C6H4O7)4(O2)4]•8H2O [J].

Kakihana, M ;

Tada, M ;

Shiro, M ;

Petrykin, V ;

Osada, M ;

Nakamura, Y .

INORGANIC CHEMISTRY, 2001, 40 (05) :891-894

[10] COORDINATION STRUCTURES FOR URANYL CARBOXYLATE COMPLEXES IN AQUEOUS-SOLUTION STUDIED BY IR AND C-13 NMR-SPECTRA [J].

KAKIHANA, M ;

NAGUMO, T ;

OKAMOTO, M ;

KAKIHANA, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (24) :6128-6136