Dip-coating thin yttria-stabilized zirconia films for solid oxide fuel cell applications

被引:67
作者
Zhang, YL [1 ]
Gao, HF [1 ]
Peng, DK [1 ]
Meng, MY [1 ]
Liu, XQ [1 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Anhua 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
suspensions; fuel cells; dip-coating; thin films;
D O I
10.1016/j.ceramint.2003.10.026
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The preparation of high-quality yttria-stabilized zirconia (YSZ) electrolyte films on porous substrates is critical to the fabrication of high-performance solid-state ionic devices such as solid oxide fuel cells (SOFCs) and gas sensors. In this paper, stable, fully dispersed YSZ suspensions were prepared. Particles zeta-potential and relative viscosity of suspensions were investigated. Thin YSZ films were deposited on NiO-YSZ anode supports with the YSZ Suspensions and then heated to 1400degreesC in air. Dense and crack-free films were obtained with thickness in the range of 20-30 muM. La0.8Sr0.2MnO3 (LSM) paste was printed on the YSZ electrolyte/anode to assemble single fuel cell and tested in the temperature range of 650-800degreesC. The open circuit voltage (OCV) of the cells reached 0.98 V and maximum power density 190 mW/cm(2) at 800degreesC, showing a reasonable performance. The deposited thin films could be considered forelectrolyte application in intermediate temperature SOFCs. (C) 2004 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:1049 / 1053
页数:5
相关论文
共 16 条
[1]   Stabilising zirconia aqueous suspensions using commercial polyvalent electrolyte solutions [J].
Briscoe, BJ ;
Khan, AU ;
Luckham, PF .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1998, 18 (14) :2169-2173
[2]   ELECTRICAL-PROPERTIES OF PLASMA-SPRAYED YTTRIA-STABILIZED ZIRCONIA FILMS [J].
CHIODELLI, G ;
MAGISTRIS, A ;
SCAGLIOTTI, M ;
PARMIGIANI, F .
JOURNAL OF MATERIALS SCIENCE, 1988, 23 (04) :1159-1163
[3]   Thin-film solid oxide fuel cell with high performance at low-temperature [J].
deSouza, S ;
Visco, SJ ;
DeJonghe, LC .
SOLID STATE IONICS, 1997, 98 (1-2) :57-61
[4]   Pressure slip casting of bimodal silicon carbide powder suspensions [J].
Ferreira, JMF ;
Diz, HMM .
CERAMICS INTERNATIONAL, 1999, 25 (06) :491-495
[5]   THIN-FILM CERAMIC ELECTROLYTES DEPOSITED ON POROUS AND NONPOROUS SUBSTRATES BY SOL-GEL TECHNIQUES [J].
KUEPER, TW ;
VISCO, SJ ;
DEJONGHE, LC .
SOLID STATE IONICS, 1992, 52 (1-3) :251-259
[6]   Influence of debinding rate, solid loading and binder formulation on the green microstructure and sintering behaviour of ceramic injection mouldings [J].
Liu, DM ;
Tseng, WJ .
CERAMICS INTERNATIONAL, 1998, 24 (06) :471-481
[7]  
MINORU I, 1997, SOLID STATE IONICS, V104, P303
[8]  
NAOKI W, 2002, THIN SOLID FILMS, V441, P268
[9]  
NINH NQ, 1993, J AM CERAM SOC, V76, P563
[10]   INFLUENCE OF VARIOUS CONSOLIDATION TECHNIQUES ON THE GREEN MICROSTRUCTURE AND SINTERING BEHAVIOR OF ALUMINA POWDERS [J].
ROOSEN, A ;
BOWEN, HK .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1988, 71 (11) :970-977