Synthesis and characterization of mesoporous silica AMS-10 with bicontinuous cubic Pn3m symmetry

被引:111
作者
Gao, Chuanbo
Sakamoto, Yasuhiro [1 ]
Sakamoto, Kazutami
Terasaki, Osamu
Che, Shunai
机构
[1] Stockholm Univ, Arrhenius Lab, S-10691 Stockholm, Sweden
[2] Shanghai Jiao Tong Univ, State Key Lab Composite Mat, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
[3] Shiseido Co LTD, Res Ctr, Yokohama, Kanagawa 2248558, Japan
关键词
D O I
10.1002/anie.200504114
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Woven into place: By precisely controlling the neutralization degree of the anionic surfactant template, mesoporous silica with different structures was prepared, such as AMS-10. Detailed characterizations of AMS-10 show that it is a novel bicontinuous cubic Pn3m mesophase. The mesostructure is composed of an interwoven enantiomeric pair of 3D networks (see picture). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码:4295 / 4298
页数:4
相关论文
共 26 条
[1]  
[Anonymous], ANGEW CHEM
[2]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[3]   The structure of MCM-48 determined by electron crystallography [J].
Carlsson, A ;
Kaneda, M ;
Sakamoto, Y ;
Terasaki, O ;
Ryoo, R ;
Joo, SH .
JOURNAL OF ELECTRON MICROSCOPY, 1999, 48 (06) :795-798
[4]   Synthesis and characterization of chiral mesoporous silica [J].
Che, S ;
Liu, Z ;
Ohsuna, T ;
Sakamoto, K ;
Terasaki, O ;
Tatsumi, T .
NATURE, 2004, 429 (6989) :281-284
[5]   A novel anionic surfactant templating route for synthesizing mesoporous silica with unique structure [J].
Che, S ;
Garcia-Bennett, AE ;
Yokoi, T ;
Sakamoto, K ;
Kunieda, H ;
Terasaki, O ;
Tatsumi, T .
NATURE MATERIALS, 2003, 2 (12) :801-805
[6]   Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties [J].
Fan, J ;
Yu, CZ ;
Gao, T ;
Lei, J ;
Tian, BZ ;
Wang, LM ;
Luo, Q ;
Tu, B ;
Zhou, WZ ;
Zhao, DY .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (27) :3146-3150
[7]  
Fan J., 2003, ANGEW CHEM, V115, P3254, DOI DOI 10.1002/ANGE.200351027
[8]  
Finnefrock A. C., 2001, ANGEW CHEM, V113, P1247
[9]  
Finnefrock AC, 2001, ANGEW CHEM INT EDIT, V40, P1207, DOI 10.1002/1521-3773(20010401)40:7<1207::AID-ANIE1207>3.0.CO
[10]  
2-S