Constitutive model for the finite deformation stress-strain behavior of poly(ethylene terephthalate) above the glass transition

被引:226
作者
Boyce, MC [1 ]
Socrate, S [1 ]
Llana, PG [1 ]
机构
[1] MIT, Dept Engn Mech, Cambridge, MA 02139 USA
基金
美国国家科学基金会;
关键词
poly(ethylene terephthalate); stress-strain behavior; glass transition temperature;
D O I
10.1016/S0032-3861(99)00406-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A constitutive model for the finite deformation stress-strain behavior of poly(ethylene terephthalate) (PET) at temperatures above the glass transition temperature is presented. In this temperature regime, the behavior of PET is strongly dependent on strain rate and temperature; PET also experiences strain-induced crystallization at these temperatures. The constitutive model accounts for the rate and temperature dependence of the stress-strain behavior by modeling the competition between molecular orientation processes and molecular relaxation processes. The model is fully three-dimensional and is shown to be in good agreement with experimental data over a wide range in strain rates and temperatures as well as under both uniaxial compression and plane strain compression loading conditions. (C) 1999 Elsevier Science Ltd. ALI rights reserved.
引用
收藏
页码:2183 / 2201
页数:19
相关论文
共 22 条
[1]  
ADAMS AM, 1994, P 9 INT C DEF YIELD
[2]   EFFECTS OF STRAIN-RATE, TEMPERATURE AND THERMOMECHANICAL COUPLING ON THE FINITE STRAIN DEFORMATION OF GLASSY-POLYMERS [J].
ARRUDA, EM ;
BOYCE, MC ;
JAYACHANDRAN, R .
MECHANICS OF MATERIALS, 1995, 19 (2-3) :193-212
[3]   A 3-DIMENSIONAL CONSTITUTIVE MODEL FOR THE LARGE STRETCH BEHAVIOR OF RUBBER ELASTIC-MATERIALS [J].
ARRUDA, EM ;
BOYCE, MC .
JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 1993, 41 (02) :389-412
[4]   EVOLUTION OF PLASTIC ANISOTROPY IN AMORPHOUS POLYMERS DURING FINITE STRAINING [J].
ARRUDA, EM ;
BOYCE, MC .
INTERNATIONAL JOURNAL OF PLASTICITY, 1993, 9 (06) :697-720
[5]   Constitutive modeling of the large strain time-dependent behavior of elastomers [J].
Bergstrom, JS ;
Boyce, MC .
JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 1998, 46 (05) :931-954
[6]   ON THE KINEMATICS OF FINITE STRAIN PLASTICITY [J].
BOYCE, MC ;
WEBER, GG ;
PARKS, DM .
JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 1989, 37 (05) :647-665
[7]   LARGE INELASTIC DEFORMATION OF GLASSY-POLYMERS .1. RATE DEPENDENT CONSTITUTIVE MODEL [J].
BOYCE, MC ;
PARKS, DM ;
ARGON, AS .
MECHANICS OF MATERIALS, 1988, 7 (01) :15-33
[8]   GLASS-RUBBER CONSTITUTIVE MODEL FOR AMORPHOUS POLYMERS NEAR THE GLASS-TRANSITION [J].
BUCKLEY, CP ;
JONES, DC .
POLYMER, 1995, 36 (17) :3301-3312
[9]   Hot-drawing of poly(ethylene terephthalate) under biaxial stress: Application of a three-dimensional glass-rubber constitutive model [J].
Buckley, CP ;
Jones, DC ;
Jones, DP .
POLYMER, 1996, 37 (12) :2403-2414
[10]   BIAXIAL ORIENTATION OF POLY(ETHYLENE-TEREPHTHALATE) .1. NATURE OF THE STRESS-STRAIN CURVES [J].
CHANDRAN, P ;
JABARIN, S .
ADVANCES IN POLYMER TECHNOLOGY, 1993, 12 (02) :119-132