New developments for the numerical analysis of spectrophotometric titrations

被引：11

作者：

Dyson, RM

Jandanklang, P

Maeder, M ^{[1
]}

Mason, CJ

Whitson, A

机构：

[1] Univ Newcastle, Dept Chem, Newcastle, NSW 2308, Australia

[2] Solvias AG, Online Technol, CH-4002 Basel, Switzerland

来源：

POLYHEDRON | 1999年 / 18卷 / 25期

关键词：

spectrophotometric titrations; numerical analysis; least-squares fit; equilibria; soft-modeling; hard-modeling;

D O I：

10.1016/S0277-5387(99)00278-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Spectrophotometric titrations are a valuable tool for the investigation of solution equilibria. Data acquisition and recent developments on methods fur the analysis of the measurements are discussed in this contribution. Hard-modeling methods are based on non-linear least-squares fitting, and algorithms have been developed which can cope with the large amount of data and parameters of multiwavelength or multivariate measurements. Good preliminary insight into the equilibria can be gained by soft-modeling methods. Neu firm-modeling methods are a compromise, combining advantages and disadvantages of the hard- and soft-modeling approaches. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：3227 / 3232

页数：6

共 31 条

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[2]

Bevington P.R., 1969, DATA REDUCTION ERROR

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