Synthesis and structural characterization of a new two-dimensional polymeric thallium(I) compound, {Tl[(H)phthalate)]}n

被引：8

作者：

Askarinejad, Azadeh ^{[1
]}

Morsali, Ali ^{[1
]}

机构：

[1] Tarbiat Modarres Univ, Sch Sci, Dept Chem, Tehran, Iran

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2006年 / 59卷 / 09期

关键词：

thallium; crystal structure; lone pair; phthalate ligand;

D O I：

10.1080/00958970500448226

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A two-dimensional polymer, {Tl[(H) phthalate)]}(n), has been synthesized and characterized by elemental analysis, IR-, H-1 NMR- and C-13 NMR spectroscopy. The single-crystal X-ray data show the coordination number Tl-I ion is six, TlO6. However, the arrangement of O-atoms suggests a gap or hole in the coordination geometry around thallium. A stereo chemically 'active' electron lone pair of Tl-I possibly occupies this 'hole'.

引用

页码：997 / 1005

页数：9

共 15 条

[1] Thallium(I) bis(mercaptoimidazolyl)borates [J].

Alvarez, HM ;

Gillespie, PA ;

Gause, CD ;

Rheingold, AL ;

Golen, JA ;

Rabinovich, D .

POLYHEDRON, 2004, 23 (04) :617-622

[2]

[Anonymous], 1997, SHELXTL 97 V5 10

[3] Concerted supramolecular moths: Linear columns and zigzag chains of multiple phenyl embraces involving Ph(4)P(+) cations in crystals [J].

Dance, I ;

Scudder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (19) :3755-3769

[4]

FADAEI MR, Z NATURFORSCH B, V60, P741

[5] Crystal engineering using bisphenols and trisphenols.: Complexes with 1,10-phenanthroline:: hydrogen-bonded chains in adducts with 4,4′-biphenol (1/1) and 4,4′-sulfonyldiphenol (2/3), π-π stacked chains in the (1/2) adduct with 4,4′-thiodiphenol, and pairwise-interwoven nets in 1,1,1-tris(4-hydroxyphenyl)ethane-1,10-phenanthroline-methanol (1/1/1) [J].

Ferguson, G ;

Glidewell, C ;

Lavender, ES .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1999, 55 :591-600

[6]

Greenwood N. N., 1986, CHEM ELEMENTS, P235

[7] THE STEREOCHEMICAL ACTIVITY OR NON-ACTIVITY OF THE INERT PAIR OF ELECTRONS ON LEAD(II) IN RELATION TO ITS COMPLEX STABILITY AND STRUCTURAL-PROPERTIES - SOME CONSIDERATIONS IN LIGAND DESIGN [J].

HANCOCK, RD ;

SHAIKJEE, MS ;

DOBSON, SM ;

BOEYENS, JCA .

INORGANICA CHIMICA ACTA, 1988, 154 (02) :229-238

[8]

Liu ZH, 2000, NEW J CHEM, V24, P1057

[9] Syntheses and characterization of thallium(I) complexes with 3-nitrophenoxide [Tl(3-np)], 4-nitrobenzoate [Tl(4-nb)] and 2,4-dinitrophenoxide [Tl(2,4-dnp)]:: X-ray crystal structures of [Tl(3-np)]n and Tl(2,4-dnp) (two new polymeric compounds) [J].

Mahjoub, AR ;

Morsali, A ;

Bagherzadeh, H .

POLYHEDRON, 2002, 21 (25-26) :2555-2560

[10]

PYYKKO P, 1997, CHEM REV, V30, P1660

← 1 2 →