Synthesis and characterization of novel phthalocyanines with four 16-membered diazadithia macrocycles

被引：59

作者：

Yilmaz, I ^{[1
]}

Bekaroglu, O ^{[1
]}

机构：

[1] TECH UNIV ISTANBUL,DEPT CHEM,TR-80626 MASLAK,ISTANBUL,TURKEY

来源：

CHEMISCHE BERICHTE | 1996年 / 129卷 / 08期

关键词：

phthalocyanines; sulphonated; diazadithiamacrocycles; pentanuclear complex;

D O I：

10.1002/cber.19961290815

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal phthalocyanines (M = Cu, Ni, Co) 3-5 bearing four 16-membered diazadithia macrocycles at the peripheral positions were prepared. Detosylation with concentrated sulfuric acid afforded products containing both sulfonated groups on the aromatic rings of the macrocyclic substituents which are excellently soluble in water and donor sites for binding four Cu-II ions to give a pentanuclear complex.

引用

页码：967 / 971

页数：5

共 26 条

[1] SYNTHESIS AND COMPLEXATION OF 1,2-BIS[(MONOAZA[15]CROWN-5)-N-YL]GLYOXIME - CRYSTAL-STRUCTURE OF (1,2-BIS[(MONOAZA[15]CROWN-5)-N-YL]GLYOXIMATO)PALLADIUM(II) [J].

AHSEN, V ;

MUSLUOGLU, E ;

GUREK, A ;

GUL, A ;

BEKAROGLU, O ;

ZEHNDER, M .

HELVETICA CHIMICA ACTA, 1990, 73 (01) :174-179

[2] SYNTHESIS AND CHARACTERIZATION OF METAL-FREE AND METAL DERIVATIVES OF A NOVEL SOLUBLE CROWN-ETHER-CONTAINING PHTHALOCYANINE [J].

AHSEN, V ;

YILMAZER, E ;

ERTAS, M ;

BEKAROGLU, O .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02) :401-406

[3] SYNTHESIS AND CHARACTERIZATION OF SOME NONUNIFORMLY SUBSTITUTED MESOGENIC PHTHALOCYANINES [J].

CHAMBRIER, I ;

COOK, MJ ;

CRACKNELL, SJ ;

MCMURDO, J .

JOURNAL OF MATERIALS CHEMISTRY, 1993, 3 (08) :841-849

[4] A SIMPLIFIED SYNTHETIC ROUTE TO POLYAZA MACROCYCLES [J].

CHAVEZ, F ;

SHERRY, AD .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (12) :2990-2992

[5] SYNTHESIS AND CHARACTERIZATION OF SOME NOVEL PHTHALOCYANINES CONTAINING BOTH OLIGO(ETHYLENEOXY) AND ALKYL OR ALKOXY SIDE-CHAINS - NOVEL UNSYMMETRICAL DISCOTIC MESOGENS [J].

CLARKSON, GJ ;

MCKEOWN, NB ;

TREACHER, KE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1995, (14) :1817-1823

[6] SYNTHESIS AND AGGREGATION PROPERTIES IN SOLUTION OF A NEW OCTASUBSTITUTED COPPER PHTHALOCYANINE - [-2,3,9,10,16,17,23,24-OCTAKIS [(DIOCTYLAMINOCARBONYL)METHOXY]PHTHALOCYANINATO-]COPPER(II) [J].

DURO, JA ;

TORRES, T .

CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (01) :269-271

[7]

Gregory P., 1991, HIGH TECHNOLOGY APPL

[8] SYNTHESIS, CHARACTERIZATION AND ELECTRICAL-PROPERTIES OF PHTHALOCYANINES SUBSTITUTED WITH 17-MEMBERED TRIOXADIAZA MACROCYCLES [J].

GUMUS, G ;

OZTURK, ZZ ;

AHSEN, V ;

GUL, A ;

BEKAROGLU, O .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (16) :2485-2489

[9]

GUMUS G, 1994, J CHEM RES, P430

[10] SYNTHESIS AND CHARACTERIZATION OF A NEW COPPER(II) PHTHALOCYANINATE SUBSTITUTED WITH 4 15-MEMBERED TETRAAZAMACROCYCLES AND ITS WATER-SOLUBLE PENTANUCLEAR COMPLEXES [J].

GUREK, A ;

AHSEN, V ;

GUL, A ;

BEKAROGLU, O .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (12) :3367-3371

← 1 2 3 →