Counter-ion effects switch ligand binding from C-2 to C-5 in kinetic carbenes formed from an imidazolium salt and IrH5(PPh3)2

被引：82

作者：

Kovacevic, A

Gründemann, S

Miecznikowski, JR

Clot, E

Eisenstein, O

Crabtree, RH

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[2] Univ Montpellier 2, LSDSMS, UMR 5636, F-34095 Montpellier, France

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 21期

关键词：

D O I：

10.1039/b207588c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Changing the counter-anion in 2-pyridylmethyl imidazolium salts (Br, BF4, PF6, SbF6) causes their kinetic reaction products with IrH5( PPh3)(2) to be switched from normal C-2 to abnormal C-5 binding.

引用

页码：2580 / 2581

页数：2

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