CdTe .2. Defect chemistry

被引:23
作者
Brebrick, RF
Fang, R
机构
[1] Mat. Science and Metallurgy Program, College of Engineering, Marquette University, Milwaukee
基金
美国国家航空航天局;
关键词
semiconductors; chalcogenides; defects; phase equilibria; electrical properties;
D O I
10.1016/0022-3697(95)00250-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A statistical thermodynamic derivation of the equilibrium equations for two defect models for CdTe(s) at high temperatures is given. In the first the predominant defects are assumed to be doubly ionizable Cd vacancy accepters and singly ionizable Te antisite donors in Te rich material and doubly ionizable Te vacancy donors in Cd rich material. A variant in which the Te antisite defect is neutral is readily extracted from the equations by setting the donor level far enough below the conduction band edge. In the second model the Te antisite defect is replaced by a neutral Te interstitial defect. The models are then applied to the high temperature data. It is concluded that the singly ionizable Te antisite model gives the best overall fit and various high temperature properties are calculated with two sets of the adjustable parameters.
引用
收藏
页码:451 / 460
页数:10
相关论文
共 15 条
[1]   PARTIAL PRESSURES IN CD-TE AND ZN-TE SYSTEMS [J].
BREBRICK, RF .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1971, 118 (12) :2014-&
[2]   PARTIAL PRESSURES + GIBBS FREE ENERGY OF FORMATION FOR CONGRUENTLY SUBLIMING CDTE(C) [J].
BREBRICK, RF ;
STRAUSS, AJ .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1964, 25 (12) :1441-&
[3]  
BREBRICK RF, 1969, J SOLID STATE CHEM, V1, P88
[4]   DEFECT STRUCTURE OF CDTE - HALL DATA [J].
CHERN, SS ;
VYDYANATH, HR ;
KROGER, FA .
JOURNAL OF SOLID STATE CHEMISTRY, 1975, 14 (01) :33-43
[5]  
De Nobel D., 1959, PHILIPS RES REP, V14, P361
[6]   VAPOR-PRESSURE SCANNING OF NONSTOICHIOMETRY IN CDTE [J].
GREENBERG, JH ;
GUSKOV, VN ;
LAZAREV, VB ;
SHEBERSHNEVA, OV .
JOURNAL OF SOLID STATE CHEMISTRY, 1993, 102 (02) :382-389
[7]   ENERGY-GAP VERSUS ALLOY COMPOSITION AND TEMPERATURE IN HG1-XCDXTE [J].
HANSEN, GL ;
SCHMIT, JL ;
CASSELMAN, TN .
JOURNAL OF APPLIED PHYSICS, 1982, 53 (10) :7099-7101
[8]  
KROGER FA, 1977, REV PHYS APPL, V12, P203
[9]   A SIMPLEX-METHOD FOR FUNCTION MINIMIZATION [J].
NELDER, JA ;
MEAD, R .
COMPUTER JOURNAL, 1965, 7 (04) :308-313
[10]   ELECTRICALLY ACTIVE POINT DEFECTS IN CADMIUM TELLURIDE [J].
SMITH, FTJ .
METALLURGICAL TRANSACTIONS, 1970, 1 (03) :617-&