Multivariate statistical process control in chromatography

被引:42
作者
Nijhuis, A [1 ]
deJong, S [1 ]
Vandeginste, BGM [1 ]
机构
[1] STATE UNIV GHENT, DEPT ORGAN CHEM, B-9000 GHENT, BELGIUM
关键词
multivariate statistical process control; Hotelling's T-2 statistic; principal component analysis; chromatography;
D O I
10.1016/S0169-7439(97)00054-3
中图分类号
TP [自动化技术、计算机技术];
学科分类号
0812 ;
摘要
The need for multivariate statistical process control (MSPC) to check the performance of processes is becoming more important as the increasing number of variables that can be measured increases. In this paper Hotelling's T-2 statistic based on PCA is used for the development of multivariate control charts. The significant principal components (PCs) are used to develop the T-2-chart and the remaining PCs contribute to the congruent to SPE-chart. Results of applying multivariate control charts in chromatography are presented. The application concerns a capillary gas chromatography analysis of the fatty acid composition in BCR162 (soya-maize oil). (C) 1997 Elsevier Science B.V.
引用
收藏
页码:51 / 62
页数:12
相关论文
共 16 条
[1]  
[Anonymous], STAT QUALITY CONTROL
[2]   SOME THEOREMS ON QUADRATIC FORMS APPLIED IN THE STUDY OF ANALYSIS OF VARIANCE PROBLEMS .1. EFFECT OF INEQUALITY OF VARIANCE IN THE ONE-WAY CLASSIFICATION [J].
BOX, GEP .
ANNALS OF MATHEMATICAL STATISTICS, 1954, 25 (02) :290-302
[3]  
Cliff N., 1987, ANAL MULTIVARIATE DA
[4]   The role of permutation tests in exploratory multivariate data analysis [J].
Dijksterhuis, GB ;
Heiser, WJ .
FOOD QUALITY AND PREFERENCE, 1995, 6 (04) :263-270
[5]  
DOES RJM, 1996, STAT PROCESBEHEERSIN
[6]  
Efron B., 1982, JACKKNIFE BOOTSTRAP, DOI DOI 10.1137/1.9781611970319
[7]   ROBUST ESTIMATES, RESIDUALS, AND OUTLIER DETECTION WITH MULTIRESPONSE DATA [J].
GNANADESIKAN, R ;
KETTENRING, JR .
BIOMETRICS, 1972, 28 (01) :81-+
[8]  
Golub G. H., 2012, Matrix computations, V3
[9]  
Jolliffe I., 2002, Principal Component Analysis, V2, DOI [10.1007/b98835, DOI 10.1007/B98835, 10.1007/0-387-22440-8_13, DOI 10.1007/0-387-22440-8_13]
[10]   PROCESS ANALYSIS, MONITORING AND DIAGNOSIS, USING MULTIVARIATE PROJECTION METHODS [J].
KOURTI, T ;
MACGREGOR, JF .
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 1995, 28 (01) :3-21