Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte)

被引：34

作者：

Ali, MM ^{[1
]}

Perzanowski, HP ^{[1
]}

Ali, SA ^{[1
]}

机构：

[1] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia

来源：

POLYMER | 2000年 / 41卷 / 15期

关键词：

polyelectrolyte; polyampholyte; poly(quaternary ammonium salt);

D O I：

10.1016/S0032-3861(99)00764-8

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The quaternary ammonium salt, N,N-diallyl-N-carboethoxymethyl-N-carbomethoxypentylammonium chloride 13, on polymerization in aqueous solution using teut-butylhydroperoxide, afforded the polyelectrolyte 14. The copolymer 15 of the monomer 13 and sulfur dioxide was synthesized in excellent yield. The polyelectrolytes 14 and 15 on acidic hydrolysis gave the poly(ampholyte-electrolytes) 16 and 17 which contain structural features common to both polyampholytes and conventional polyelectrolytes. The solution properties of these polymers are discussed in detail. The poly(ampholyte-electrolyte)s, 16 and 17 are shown to have considerably higher viscosity than their corresponding polyelectrolytes 14 and 15. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5591 / 5600

页数：10

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