First syntheses of model long-chain trichloro[ω-(trimethylsilyl)alkynyl]silanes suitable for self-assembled monolayers on silicon surfaces

被引：10

作者：

Banaszak, Estelle ^{[1
,2
]}

Xu, Li-Wen ^{[1
,2
]}

Bardeau, Jean-Francois ^{[1
,3
]}

Castanet, Anne-Sophie ^{[1
,2
]}

Mortier, Jacques ^{[1
,2
]}

机构：

[1] Univ Maine, F-72085 Le Mans 9, France

[2] Fac Sci & Tech, CNRS, UMR 6011,FR N 2575, Unite Chim Organ Mol & Macromol, F-72085 Le Mans 9, France

[3] Fac Sci & Tech, CNRS, UMR 6011,FR N 2575, Lab Phys Etat Condense, F-72085 Le Mans 9, France

来源：

TETRAHEDRON | 2009年 / 65卷 / 20期

关键词：

Trichloro omega-alkynylsilanes; Self-assembled monolayers; ALKYNYL GROUP-TRANSFER; CLICK CHEMISTRY; SOLVENT; ACIDS; POLYMERIZATION; DERIVATIVES; REACTIVITY; CU;

D O I：

10.1016/j.tet.2009.03.046

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

The preparation of the title compounds involves the introduction of the required Me3SiC C and trichlorosilyl groups at the termini of the alkyl chain via derivatization of easily accessible and inexpensive materials/reagents. Trichloro[omega-(trimethylsilyl)alkynyl]silanes are useful for the linkage to a hydroxylated silicon surface for multilayer formation and for further chemical modification of the tail group of the monolayer. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：3961 / 3966

页数：6

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