Polymerization of a butadiyne derivative in crystalline state stimulated by radical initiators

被引：11

作者：

Arai, Makoto ^{[1
]}

Okada, Shuji ^{[1
]}

机构：

[1] Yamagata Univ, Dept Polymer Sci & Engn, Fac Engn, Yonezawa, Yamagata 9928510, Japan

来源：

CHEMISTRY LETTERS | 2006年 / 35卷 / 09期

关键词：

D O I：

10.1246/cl.2006.1012

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Solid-state polymerization of a butadiyne derivative initiated by radical species was investigated for the first time. In the nanocrystals, monomers were fully converted to the polydiacetylenes as the case of conventional photopolymerization. In bulk crystals, polymerization occurred only the parts near the specific crystal surfaces.

引用

页码：1012 / 1013

页数：2

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